Dissipation-scale fluctuations and mixing transition in turbulent flows

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Abstract: Small separation between reactants, not exceeding 10−8−10−7cm, is the necessary condition for various chemical reactions. It is shown that random advection and stretching by turbulence leads to formation of scalar-enriched sheets of {it strongly fluctuating thickness} etac. The molecular-level mixing is achieved by diffusion across these sheets (interfaces) separating the reactants. Since diffusion time scale is audproptoetac2, the knowledge of probability density Q(etac,Re) is crucial for evaluation of chemical reaction rates. In this paper we derive the probability density Q(etac,Re,Sc) and predict a transition in the reaction rate behavior from calRproptosqrtRe (Releq104) to the high-Re asymptotics calRproptoRe0. The theory leads to an approximate universality of transitional Reynolds number Retrapprox104. It is also shown that if chemical reaction involves short-lived reactants, very strong anomalous fluctuations of the length-scale etac may lead to non-negligibly small reaction rates.












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