Continuous particles in the canonical ensemble as an abstract polymer gas

DOI10.1007/S10955-013-0731-YzbMATH Open1272.82013arXiv1301.0107OpenAlexW2031933902MaRDI QIDQ358671FDOQ358671

Thiago Morais, Aldo Procacci

Publication date: 9 August 2013

Published in: Journal of Statistical Physics (Search for Journal in Brave)

Abstract: We revisit the expansion recently proposed by Pulvirenti and Tsagkarogiannis for a system of $N$ continuous particles in the canonical ensemble. Under the sole assumption that the particles interact via a tempered and stable pair potential and are subjected to the usual free boundary conditions, we show the analyticity of the Helmholtz free energy at low densities and, using the Penrose tree graph identity, we establish a lower bound for the convergence radius which happens to be identical to the lower bound of the convergence radius of the virial series in the grand canonical ensemble established by Lebowitz and Penrose in 1964. We also show that the (Helmholtz) free energy can be written as a series in power of the density whose $k$ order coefficient coincides, modulo terms $o(N)/N$, with the $k$-order virial coefficient divided by $k+1$, according to its expression in terms of the $m$-order (with $mlek+1$) simply connected cluster integrals first given by Mayer in 1942. We finally give an upper bound for the $k$-order virial coefficient which slightly improves, at high temperatures, the bound obtained by Lebowitz and Penrose.

Full work available at URL: https://arxiv.org/abs/1301.0107

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zbMATH Keywords

continuous particle systemcanonical ensemblePenrose tree graph identitypolymer gas

Mathematics Subject Classification ID

Trees (05C05) Continuum models (systems of particles, etc.) arising in equilibrium statistical mechanics (82B21) Interacting particle systems in time-dependent statistical mechanics (82C22)

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Cited In (10)

• The virial series for a gas of particles with uniformly repulsive pairwise interaction and its relation with the approach to the mean field
• Convergence of virial expansions for some anyonic-like systems
• Cluster expansion for the Ising model in the canonical ensemble
• Virial series for a system of classical particles interacting through a pair potential with negative minimum
• Convergence of density expansions of correlation functions and the Ornstein-Zernike equation
• A solution to the combinatorial puzzle of Mayer's virial expansion
• Convergence of Mayer and Virial expansions and the Penrose tree-graph identity
• On the analyticity of the pressure for a non-ideal gas with high density boundary conditions
• Virial expansion bounds
• Multispecies virial expansions

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