The asymptotic behaviour of the ground state energy of the Müller functional for heavy atoms

DOI10.1088/1751-8113/42/8/085201MaRDI QIDQ3608949zbMATHOpenAlexFDO

Authors Heinz Siedentop

Publication date 6 March 2009

Published in Journal of Physics A: Mathematical and Theoretical (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/0811.2453

Mathematics Subject Classification ID

Atomic physics (81V45)

Abstract: The ground state energy of the Mueller functional of large (neutral) atoms of atomic number Z agrees with the quantum mechanical ground state energy up to order o(Z to the 5/3). ----- Die Grundzustandsenergie des Muellerfunktionals von grossen (neutralen) Atomen der Ordnungszahl Z stimmt mit der quantenmechanischen Grundzustandsenergie bis zur Ordnung o(Z hoch 5/3) ueberein.

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Cited in

(7)

• Kinetic energy estimates for the accuracy of the time-dependent Hartree-Fock approximation with Coulomb interaction
• The maximal excess charge in Müller density-matrix-functional theory
• The maximal excess charge for a family of density-matrix-functional theories including Hartree-Fock and Müller theories
• The Scott conjecture for large Coulomb systems: a review
• Binding of atoms in Müller theory
• A short proof of the ionization conjecture in Müller theory
• Long-range asymptotic behaviour of the ground-state electron density in He-like ions as a function of atomic number

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