Electromigration dispersion in capillary electrophoresis

DOI10.1007/S11538-011-9708-7MaRDI QIDQ417354zbMATH OpenOpenAlexWikidataFDO

Authors Sandip Ghosal, Zhen Chen

Publication date 14 May 2012

Published in Bulletin of Mathematical Biology (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1203.1062, http://europepmc.org/articles/pmc3291716

zbMATH Keywords

capillary electrophoresiselectromigration dispersion

Mathematics Subject Classification ID

Biochemistry, molecular biology (92C40)

Abstract: In a previous paper (S. Ghosal and Z. Chen Bull. Math. Biol. 2010, vol. 72, pg. 2047) it was shown that the evolution of the solute concentration in capillary electrophoresis is described by a nonlinear wave equation that reduced to Burger's equation if the nonlinearity was weak. It was assumed that only strong electrolytes (fully dissociated) were present. In the present paper it is shown that the same governing equation also describes the situation where the electrolytic buffer consists of a single weak acid (or base). A simple approximate formula is derived for the dimensionless peak variance which is shown to agree well with published experimental data.

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Cites work

• Electromigration dispersion in a capillary in the presence of electro-osmotic flow
• Nonlinear waves in capillary electrophoresis

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(8)

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• Electromigration dispersion in a capillary in the presence of electro-osmotic flow
• scientific article; zbMATH DE number 2000296 (Why is no real title available?)
• The effect of wall interactions in capillary-zone electrophoresis
• High-order numerical solution of viscous Burgers' equation using an extended Cole-Hopf barycentric Gegenbauer integral pseudospectral method
• The nonlinear electromigration of analytes into confined spaces
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• Nonlinear waves in capillary electrophoresis

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