Electron correlation energy in confined two-electron systems

DOI10.1016/J.PHYSLETA.2010.08.071MaRDI QIDQ418557zbMATH OpenOpenAlexFDO

Authors C. L. Wilson, H. E. jun. Montgomery, K. D. Sen, D. C. Thompson

Publication date 29 May 2012

Published in Physics Letters. A (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1008.4366

Mathematics Subject Classification ID

Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Atomic physics (81V45)

Abstract: Radial, angular and total correlation energies are calculated for four two-electron systems with atomic numbers Z=0-3 confined within an impenetrable sphere of radius R. We report accurate results for the non-relativistic, restricted Hartree-Fock and radial limit energies over a range of confinement radii from 0.05 - 10 a0. At small R, the correlation energies approach limiting values that are independent of Z while at intermediate R, systems with Z > 1 exhibit a characteristic maximum in the correlation energy resulting from an increase in the angular correlation energy which is offset by a decrease in the radial correlation energy.

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Cites work

• scientific article; zbMATH DE number 3087947 (Why is no real title available?)
• Correlation Energy of an Electron Gas at High Density
• On the Interaction of Electrons in Metals
• Spherically compressed helium atom described by perturbative and variational methods
• Superposition of Configurations
• The compressed helium atom treated variationally via a correlated Hylleraas wave function
• The ground state energy of a helium atom under strong confinement

Cited in

(14)

• Exact wave functions for concentric two-electron systems
• Co-spherical electronic configuration of the helium-like atomic systems
• Correlated kinetic energy density functional of ground states of harmonically confined two-electron atoms for arbitrary interparticle interaction
• Electron correlation in He and isoelectronic ions
• Effects of hydrostatic pressure and polaronic effects on the correlation energies in a spherical quantum dot
• Exchange energy for two-active-electron diatomic systems within the surface integral method
• The two-electron atomic systems. S-states
• A Jastrow correlation factor for two-dimensional parabolic quantum dots
• Indirect Coulomb energy for two-dimensional atoms
• Subspace density of the first excited state for two harmonically interacting electrons with isotropic harmonic confinement
• Pair function at coincidence and ground-state energy for interacting systems of two fermions with isotropic harmonic confinement and antiparallel spins
• Coulomb, exchange, kinetic, nuclear attraction and ionization energies of two-electron quantum dot with finite confinement potential
• Rigorous energy bounds for two-electron systems
• A comparative study of two-electron systems with screened Coulomb potentials

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