On the mathematical nature of Guseinov's rearranged one-range addition theorems for Slater-type functions

DOI10.1007/S10910-011-9914-4zbMATH Open1317.81121arXiv1107.4670OpenAlexW2964160088MaRDI QIDQ424197FDOQ424197

Authors: Ernst Joachim Weniger 

Publication date: 31 May 2012

Published in: Journal of Mathematical Chemistry (Search for Journal in Brave)

Abstract: Starting from one-range addition theorems for Slater-type functions, which are expansion in terms of complete and orthonormal functions based on the generalized Laguerre polynomials, Guseinov constructed addition theorems that are expansions in terms of Slater-type functions with a common scaling parameter and integral principal quantum numbers. This was accomplished by expressing the complete and orthonormal Laguerre-type functions as finite linear combinations of Slater-type functions and by rearranging the order of the nested summations. Essentially, this corresponds to the transformation of a Laguerre expansion, which in general only converges in the mean, to a power series, which converges pointwise. Such a transformation is not necessarily legitimate, and this contribution discusses in detail the difference between truncated expansions and the infinite series that result in the absence of truncation

Full work available at URL: https://arxiv.org/abs/1107.4670

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zbMATH Keywords

Laguerre expansionpower seriesaddition theoremSlater-type function

Mathematics Subject Classification ID

Selfadjoint operator theory in quantum theory, including spectral analysis (81Q10) Perturbation theories for operators and differential equations in quantum theory (81Q15)

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Cited In (3)

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• JRAF: a Julia package for computation of relativistic molecular auxiliary functions

Uses Software

• Digital Library of Mathematical Functions

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