Kinetics of charge inversion

DOI10.1088/0305-4470/36/22/305MaRDI QIDQ4451141zbMATH OpenOpenAlexFDO

Authors Yan Levin, Jeferson J. Arenzon

Publication date 23 February 2004

Published in Journal of Physics A: Mathematical and General (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0210267

zbMATH Keywords

overchargingcolloidal suspensionscharge inversionelectrostatic correlations

Mathematics Subject Classification ID

Electro- and magnetostatics (78A30) Motion of charged particles (78A35)

Abstract: Colloidal suspensions and polyelectrolyte solutions containing multivalent counterions can exhibit some very counter-intuitive behavior usually associated with the low temperature physics. There are two particularly striking phenomena resulting from strong electrostatic correlations. One is the like-charge attraction and the second is the polyion overcharging. In this contribution we will concentrate on the problem of overcharging. In particular we will explore the kinetic limitation to colloidal charge inversion in suspensions containing multivalent counterions.

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