Stereoisograms of trigonal bipyramidal compounds. II: RS-stereogenicity/RS-stereoisomerism versus stereogenicity/stereoisomerism, leading to a revised interpretation of Berry's pseudorotation

DOI10.1007/S10910-012-0007-9MaRDI QIDQ445418zbMATH OpenOpenAlexFDO

Authors Shinsaku Fujita

Publication date 24 August 2012

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1007/s10910-012-0007-9

zbMATH Keywords

stereoisogram\(C/A\)-descriptor\(RS\)-diastereomericBerry's pseudorotationtrigonal bipyramidal complex

Mathematics Subject Classification ID

Molecular structure (graph-theoretic methods, methods of differential topology, etc.) (92E10)

Recommendations

• Stereoisograms of trigonal bipyramidal compounds. I: Chirality and \(RS\)-stereogenicity free from the conventional ``chirality and ``stereogenicity
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• Three aspects of an absolute configuration on the basis of the stereoisogram approach and revised terminology on related stereochemical concepts
• Importance of the proligand-promolecule model in stereochemistry. II: The stereoisogram approach to stereoisomeric features of prismane derivatives

Cites work

• Integrated discussion on stereogenicity and chirality for restructuring stereochemistry
• Symmetry and combinatorial enumeration in chemistry.
• Theory of organic stereoisomerism in harmony with molecular symmetry

Cited in

(3)

• Relativity and the Jahn-Teller, Berry pseudorotations of TBP clusters: group theory, spin-orbit and combinatorial nuclear spin statistics of TBP Desargues-Levi isomerization graph
• Stereoisograms of trigonal bipyramidal compounds. I: Chirality and \(RS\)-stereogenicity free from the conventional ``chirality and ``stereogenicity
• Symmetry-itemized enumeration of quadruplets of \textit{RS}-stereoisomers. I: The fixed-point matrix method of the USCI approach combined with the stereoisogram approach

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