Arbitrarily accurate eigenvalues for one-dimensional polynomial potentials

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Publication:4469901




Abstract: We show that the Riccati form of the Schrodinger equation can be reformulated in terms of two linear equations depending on an arbitrary function G. When G and the potential are polynomials, the solutions of these two equations are entire functions (L and K) and the zeroes of K are identical to those of the wave function. Requiring such a zero at a large but finite value of the argument yields the low energy eigenstates with exponentially small errors. Judicious choice of G can improve dramatically the numerical treatment. The method yields many significant digits with modest computer means.









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