Arbitrarily accurate eigenvalues for one-dimensional polynomial potentials
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Publication:4469901
Eigenvalues, estimation of eigenvalues, upper and lower bounds of ordinary differential operators (34L15) Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Numerical solution of eigenvalue problems involving ordinary differential equations (65L15) Software, source code, etc. for problems pertaining to quantum theory (81-04)
Abstract: We show that the Riccati form of the Schrodinger equation can be reformulated in terms of two linear equations depending on an arbitrary function G. When and the potential are polynomials, the solutions of these two equations are entire functions (L and K) and the zeroes of K are identical to those of the wave function. Requiring such a zero at a large but finite value of the argument yields the low energy eigenstates with exponentially small errors. Judicious choice of G can improve dramatically the numerical treatment. The method yields many significant digits with modest computer means.
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