Molecular predissociation resonances below an energy level crossing

DOI10.3233/ASY-171453MaRDI QIDQ4579875zbMATH OpenFDO

Authors Sohei Ashida

Publication date 10 August 2018

Published in Asymptotic Analysis (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1707.07963

zbMATH Keywords

Born-Oppenheimer approximationdifferential systemeigenvalue crossingresonancessemiclassical analysis

Mathematics Subject Classification ID

Resonance in context of PDEs (35B34) Schrödinger operator, Schrödinger equation (35J10) Asymptotic distributions of eigenvalues in context of PDEs (35P20) NLS equations (nonlinear Schrödinger equations) (35Q55) Molecular physics (81V55)

Abstract: We study the resonances of $2imes2$ systems of one dimensional Schr"odinger operators which are related to the mathematical theory of molecular predissociation. We determine the precise positions of the resonances with real parts below the energy where bonding and anti-bonding potentials intersect transversally. In particular, we find that imaginary parts (widths) of the resonances are exponentially small and that the indices are determined by Agmon distances for the minimum of two potentials.

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• Widths of highly excited resonances in multidimensional molecular predissociation
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