The Hellmann-Feynman theorem for statistical averages

DOI10.1007/S10910-014-0368-3MaRDI QIDQ460963zbMATH OpenOpenAlexFDO

Authors Francisco M. Fernández

Publication date 9 October 2014

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1211.5958

zbMATH Keywords

commuting observablesdegenerate statesHellmann-Feynman theoremstatistical averages

Mathematics Subject Classification ID

Selfadjoint operator theory in quantum theory, including spectral analysis (81Q10) Molecular physics (81V55)

Abstract: We discuss the Hellmann-Feynman theorem for degenerate states and its application to the calculation of the derivatives of statistical averages with respect to external parameters.

Cites work

• Forces in Molecules

Cited in

(2)

• On the Hellmann-Feynman theorem in statistical mechanics
• Generalized Hellmann-Feynman theorem for ensemble average expressed in the formalism of pure state expectation

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