Phase Space Analysis of the Nonexistence of Dynamical Matching in a Stretched Caldera Potential Energy Surface

DOI10.1142/S0218127419500573zbMATH Open1412.34159arXiv1812.02328MaRDI QIDQ4632161FDOQ4632161

Authors: M. Katsanikas, Stephen Wiggins 

Publication date: 26 April 2019

Published in: International Journal of Bifurcation and Chaos in Applied Sciences and Engineering (Search for Journal in Brave)

Abstract: In this paper we continue our studies of the two dimensional caldera potential energy surface in a parametrized family that allows for a study of the effect of symmetry on the phase space structures that govern how trajectories enter, cross, and exit the region of the caldera. As a particular form of trajectory crossing, we are able to determine the effect of symmetry and phase space structure on dynamical matching. We show that there is a critical value of the symmetry parameter which controls the phase space structures responsible for the manner of crossing, interacting with the central region (including trapping in this region) and exiting the caldera. We provide an explanation for the existence of this critical value in terms of the behavior of the Henon stability parameter for the associated periodic orbits.

Full work available at URL: https://arxiv.org/abs/1812.02328

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zbMATH Keywords

symmetryHamiltonian systeminvariant manifoldsperiodic orbitschemical reaction dynamicsphase space transportPoincaré sectioncaldera potential

Mathematics Subject Classification ID

Qualitative investigation and simulation of ordinary differential equation models (34C60) Topological structure of integral curves, singular points, limit cycles of ordinary differential equations (34C05) Invariant manifolds for ordinary differential equations (34C45)

Cites Work

• Title not available (Why is that?)
• Phase space structure and transport in a caldera potential energy surface

Cited In (15)

• Bifurcation of dividing surfaces constructed from period-doubling bifurcations of periodic orbits in a caldera potential energy surface
• The bifurcations of the critical points and the role of depth in a symmetric Caldera potential energy surface
• Phase space transport in a symmetric Caldera potential with three index-1 saddles and no minima
• The influence of asymmetry on the dynamics associated with a Caldera potential energy surface
• Phase space transport and dynamical matching in a Caldera-type Hamiltonian system
• The nature of reactive and non-reactive trajectories for a three dimensional Caldera potential energy surface
• From Poincaré maps to Lagrangian descriptors: the case of the valley ridge inflection point potential
• Phase space structure and transport in a caldera potential energy surface
• Detection of dynamical matching in a Caldera Hamiltonian system using Lagrangian descriptors
• The generalization of the periodic orbit dividing surface for Hamiltonian systems with three or more degrees of freedom-III
• The generalization of the periodic orbit dividing surface for Hamiltonian systems with three or more degrees of freedom -- IV
• 3D generating surfaces in Hamiltonian systems with three degrees of freedom. I
• 3D generating surfaces in Hamiltonian systems with three degrees of freedom. II
• 2D generating surfaces and dividing surfaces in Hamiltonian systems with three degrees of freedom
• Periodic orbit dividing surfaces in a quartic Hamiltonian system with three degrees of freedom. I

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