Operator method for nonperturbative calculation of the thermodynamic values in quantum statistics: diatomic molecular gas

DOI10.1088/0305-4470/37/42/001MaRDI QIDQ4662124zbMATH OpenOpenAlexFDO

Authors

Publication date 30 March 2005

Published in Journal of Physics A: Mathematical and General (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/quant-ph/0309155, http://elib.bsu.by/handle/123456789/14544

Mathematics Subject Classification ID

Quantum equilibrium statistical mechanics (general) (82B10) Statistical mechanics of gases (82D05)

Abstract: Operator method and cumulant expansion are used for nonperturbative calculation of the partition function and the free energy in quantum statistics. It is shown for Boltzmann diatomic molecular gas with some model intermolecular potentials that the zeroth order approximation of the proposed method interpolates the thermodynamic values with rather good accuracy in the entire range of both the Hamiltonian parameters and temperature. The systematic procedure for calculation of the corrections to the zeroth order approximation is also considered.

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Cited in

(1)

• Operator method for nonperturbative description of quantum systems

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