Phase Transition in a One-dimensional Extended Peierls–Hubbard Model with a Pulse of Oscillating Electric Field: II. Linear Behavior in Neutral-to-Ionic Transition

DOI10.1143/JPSJ.73.2879MaRDI QIDQ4669559zbMATH OpenFDO

Authors Kenji Yonemitsu

Publication date 15 April 2005

Published in Journal of the Physical Society of Japan (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0408300

zbMATH Keywords

charge-transfer complexdynamicsneutral-ionic transitionphotoinduced phase transitiontime-dependent Schrödinger equationTTF-CA

Mathematics Subject Classification ID

Quantum dynamics and nonequilibrium statistical mechanics (general) (82C10) Dynamic and nonequilibrium phase transitions (general) in statistical mechanics (82C26)

Abstract: Dynamics of charge density and lattice displacements after the neutral phase is photoexcited is studied by solving the time-dependent Schr"odinger equation for a one-dimensional extended Peierls-Hubbard model with alternating potentials. In contrast to the ionic-to-neutral transition studied previously, the neutral-to-ionic transition proceeds in an uncooperative manner as far as the one-dimensional system is concerned. The final ionicity is a linear function of the increment of the total energy. After the electric field is turned off, the electronic state does not significantly change, roughly keeping the ionicity, even if the transition is not completed, because the ionic domains never proliferate. As a consequence, an electric field with frequency just at the linear absorption peak causes the neutral-to-ionic transition the most efficiently. These findings are consistent with the recent experiments on the mixed-stack organic charge-transfer complex, TTF-CA. We artificially modify or remove the electron-lattice coupling to discuss the origin of such differences between the two transitions.

Recommendations

• Phase Transition in a One-dimensional Extended Peierls–Hubbard Model with a Pulse of Oscillating Electric Field: I. Threshold Behavior in Ionic-to-Neutral Transition
• Phase Transition in a One-dimensional Extended Peierls–Hubbard Model with a Pulse of Oscillating Electric Field: III. Interference Caused by a Double Pulse
• scientific article; zbMATH DE number 1866972
• Nonlinear lattice relaxation mechanism for photoexcited dimetal-hallide chain compounds
• Nature of the self-trapping transition in a one-dimensional Holstein-Hubbard model

Cited in

(3)

• Phase Transition in a One-dimensional Extended Peierls–Hubbard Model with a Pulse of Oscillating Electric Field: I. Threshold Behavior in Ionic-to-Neutral Transition
• Phase Transition in a One-dimensional Extended Peierls–Hubbard Model with a Pulse of Oscillating Electric Field: III. Interference Caused by a Double Pulse
• Nonlinear lattice relaxation mechanism for photoexcited dimetal-hallide chain compounds

This page was built for publication: Phase Transition in a One-dimensional Extended Peierls–Hubbard Model with a Pulse of Oscillating Electric Field: II. Linear Behavior in Neutral-to-Ionic Transition

Report a bug (only for logged in users!)Click here to report a bug for this page (MaRDI item Q4669559)