ELECTRODIFFUSIONAL FREE BOUNDARY PROBLEM IN CONCENTRATION POLARIZATION IN ELECTRODIALYSIS

DOI10.1142/S0218202596000250MaRDI QIDQ4895074zbMATHOpenAlexFDO

Authors

Publication date 9 March 1997

Published in M\(^3\)AS. Mathematical Models \& Methods in Applied Sciences (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1142/s0218202596000250

zbMATH Keywords

electrochemical potentialsconventional diffusion problemdiffusional free boundary problemelectric potential profileselectrodiffusion in an electrolyteexplicit ionic concentrationionic fluxesspace charge zone

Mathematics Subject Classification ID

Singular perturbations in context of PDEs (35B25) PDEs in connection with optics and electromagnetic theory (35Q60) Free boundary problems for PDEs (35R35) Motion of charged particles (78A35)

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(9)

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• Ambipolar diffusion in the low frequency impedance response of electrolytic cells
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• Electrodiffusional free boundary problem, in a bipolar membrane (semiconductor diode), at a reverse bias for constant current
• “Concentrated capacity” model of ion-exchange funneling in a modified (thin film coated) heterogeneous electrodialysis membrane
• On a Neumann boundary value problem for the Painlevé II equation in two-ion electro-diffusion
• Improved current-voltage approximations for currents exceeding the diffusion limit

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