The Soret and Dufour effects in statistical dynamics
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Publication:4946512
Abstract: We set up a discrete space-time dynamical model of molecules with thermalised kinetic energy and repulsive cores, in an external potential. The state is specified by a probability on the sample space. One time-step is given by a bistochastic map, followed by a local thermalising map. The model obeys the first and second laws of thermodynamics. The continuum limit, obtained using a MAPLE program, gives rise to coupled nonlinear reaction-diffusion equations for the density and temperature fields. The system obeys Onsager symmetry and exhibits the Soret and Dufour effects.
Cited in
(7)- On the Diffusion Coefficient: The Einstein Relation and Beyond
- Nonlinear heat equation and thermodiffusion
- Two-level diffusion, random walk and uniqueness
- Classical and quantum probability
- Hydrodynamics in an external field
- Random walk, Rayleigh-Kac' scheme and diffusion equation
- Global and exploding solutions in a model of self-gravitating systems.
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