Work fluctuation theorems and free energy from kinetic theory

DOI10.1088/1742-5468/AA9F48zbMATH Open1459.82262arXiv1712.01017OpenAlexW3104602010MaRDI QIDQ4964429FDOQ4964429

Authors: J. Javier Brey, M. J. Ruiz-Montero, Alvaro Domínguez 

Publication date: 2 March 2021

Published in: Journal of Statistical Mechanics: Theory and Experiment (Search for Journal in Brave)

Abstract: The formulation of the First and Second Principles of thermodynamics for a particle in contact with a heat bath and submitted to an external force is analyzed, by means of the Boltzmann-Lorentz kinetic equation. The possible definitions of the thermodynamic quantities are discussed in the light of the H theorem verified by the distribution of the particle. The work fluctuation relations formulated by Bochkov and Kuzovlev, and by Jarzynski, respectively, are derived from the kinetic equation. In addition, particle simulations using both the direct simulation Monte Carlo method and Molecular Dynamics, are used to investigate the practical accuracy of the results. Work distributions are also measured, and they turn out to be rather complex. On the other hand, they seem to depend very little, if any, on the interaction potential between the intruder and the bath.

Full work available at URL: https://arxiv.org/abs/1712.01017

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Mathematics Subject Classification ID

Kinetic theory of gases in time-dependent statistical mechanics (82C40)

Cites Work

• Title not available (Why is that?)
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• Nonequilibrium work theorem for a system strongly coupled to a thermal environment
• Statistics of work and fluctuation theorems for microcanonical initial states

Cited In (4)

• Convergence of thermodynamic quantities and work fluctuation theorems in the presence of random protocols
• Electromagnetic gauge-freedom and work
• Thermodynamic work statistics for Ornstein-Uhlenbeck-type heat baths
• Work fluctuation, entropy, and time’s arrow in time-asymmetric engine cycles

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