The Green's function approach to the Fock expansion calculations of two-electron atoms

DOI10.1088/1751-8121/AAA2CEMaRDI QIDQ5373944zbMATH OpenOpenAlexFDO

Authors Evgeny Z. Liverts, Nir Barnea

Publication date 6 April 2018

Published in Journal of Physics A: Mathematical and Theoretical (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1705.09125

zbMATH Keywords

Fock expansionGreen's functionhelium-like atomstwo-particle coalescences

Mathematics Subject Classification ID

Green's functions for elliptic equations (35J08) Atomic physics (81V45)

Abstract: The renewed Green's function approach to calculating the angular Fock coefficients, $ps{i}_{k,p}(alpha,heta)$ is presented. The final formulas are simplified and specified to be applicable for analytical as well as numerical calculations. The Green's function formulas with the hyperspherical angles $heta=0,pi$ (arbitrary $alpha$) or $alpha=0,pi$ (arbitrary $heta$) are indicated as corresponding to the angular Fock coefficients possessing physical meaning. The most interesting case of $heta=0$ corresponding to a collinear arrangement of the particles is studied in detail. It is emphasized that this case represents the generalization of the specific cases of the electron-nucleus ($alpha=0$) and electron-electron ($alpha=pi/2$) coalescences. It is shown that the Green's function method for $heta=0$ enables us to calculate any component/subcomponent of the angular Fock coefficient in the form of a single series representation with arbitrary angle $heta$. Those cases, where the Green's function approach can not be applied, are thoroughly studied, and the corresponding solutions are found.

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Cited in

(3)

• Co-spherical electronic configuration of the helium-like atomic systems
• A unified treatment of the non-relativistic and relativistic hydrogen atom II: the Green functions
• Two-time Green's function method in quantum electrodynamics of high-\(Z\) few-electron atoms

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