Asymptotics of the ground state energy in the relativistic settings

DOI10.1090/SPMJ/1552MaRDI QIDQ5743353zbMATH OpenOpenAlexWikidataFDO

Authors Victor Ivrii

Publication date 9 May 2019

Published in St. Petersburg Mathematical Journal (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1707.07014

zbMATH Keywords

microlocal analysisThomas-Fermi theoryScott correction termrelativistic Schrödinger operatorsharp spectral asymptoticsheavy atoms and molecules

Mathematics Subject Classification ID

Estimates of eigenvalues in context of PDEs (35P15) Semiclassical techniques, including WKB and Maslov methods applied to problems in quantum theory (81Q20) Atomic physics (81V45) Molecular physics (81V55)

Abstract: The purpose of this paper is to derive sharp asymptotics of the ground state energy for the heavy atoms and molecules in the relativistic settings, and, in particular, to derive relativistic Scott correction term and also Dirac, Schwinger and relativistic correction terms. Also we will prove that Thomas-Fermi density approximates the actual density of the ground state, which opens the way to estimate the excessive negative and positive charges and the ionization energy.

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Cites work

• scientific article; zbMATH DE number 3533409 (Why is no real title available?)
• scientific article; zbMATH DE number 1173680 (Why is no real title available?)
• An uncertainty principle for fermions with generalized kinetic energy
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• Relativistic Scott correction in self-generated magnetic fields
• Scott correction for large atoms and molecules in a self-generated magnetic field
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Cited in

(9)

• Localization Error Estimate for the Massless Relativistic Kinetic Energy Operator
• Variational energy spectra of relativistic Hamiltonians
• The ground state energy of heavy atoms: the leading correction
• The magnetic Scott correction for relativistic matter at criticality
• scientific article; zbMATH DE number 4099804 (Why is no real title available?)
• The energy of heavy atoms according to Brown and Ravenhall: the Scott correction
• Infinite volume asymptotics of the ground state energy in a scaled Poissonian potential
• On the construction of asymptotic states for some relativistic interacting quantum field models with indefinite metric
• scientific article; zbMATH DE number 2059319 (Why is no real title available?)

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