About Chemical Modifications of Finite Dimensional QED Models

DOI10.33581/1561-4085-2021-24-3-230-241MaRDI QIDQ6132590zbMATH OpenOpenAlexFDO

Authors V. Afanasyev, Hui-Hui Miao

Publication date 17 August 2023

Published in Nonlinear Phenomena in Complex Systems (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/2107.04673

zbMATH Keywords

dark stateartificial atomsfinite-dimensional quantum electrodynamics

Mathematics Subject Classification ID

Formal methods and deformations in algebraic geometry (14D15) Electromagnetic interaction; quantum electrodynamics (81V10) Atomic physics (81V45) Chemical kinetics in thermodynamics and heat transfer (80A30) Open systems, reduced dynamics, master equations, decoherence (81S22) Dark matter and dark energy (83C56)

Abstract: Suggestion of modifications of finite-dimensional QED models are proposed for interpreting chemical reactions in terms of artificial atoms and molecules on quantum dots placed in optical cavities. Moving both photons and atoms is possible between the cavities. Super dark states of diatomic systems are described, in which the motion of atoms between cavities is impossible due quantum interference. Chemical processes with two level atoms and three level atoms with lambda spectrum are schematically modeled by solving the single quantum master equation with the Lindblad operators of photon leakage from the cavity and influx into it; association and dissociation reactions then differ only in the initial states. An example is given of the optical interpretation of the transition of an electron from atom to atom in terms of the multilevel Tavis-Cummings-Hubbard model with an estimate of the accuracy. Polyatomic chemical reactions are too complex for accurate modeling. Our method of rough interpretation helps to obtain their long-term results, for example, the form of stationary states of reagents, such as dark and super dark states.

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