Specifics of thermodynamic description of nanocrystals

DOI10.1140/EPJB/E2013-31088-2MaRDI QIDQ6135211zbMATH OpenOpenAlexFDO

Authors Anatolii I. Karasevskii

Publication date 26 July 2023

Published in The European Physical Journal B. Condensed Matter and Complex Systems (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1301.3310

zbMATH Keywords

mesoscopic and nanoscale systems

Mathematics Subject Classification ID

Statistical mechanics of crystals (82D25)

Abstract: A method of statistical description of thermodynamic properties of nanocrystals is developed. It is established that size-dependent quantization of vibrational modes results in formation of excess pressure of the phonon gas acting outwards the crystal. Based on the concept of the phonon gas pressure, size dependence of thermodynamic properties of nanocrystals was described, and size influence on a shift of a phase transformation temperature was explained.

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(9)

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