Specifics of thermodynamic description of nanocrystals

DOI10.1140/EPJB/E2013-31088-2zbMATH Open1515.82147arXiv1301.3310OpenAlexW3098925255MaRDI QIDQ6135211FDOQ6135211

Anatolii I. Karasevskii

Publication date: 26 July 2023

Published in: The European Physical Journal B. Condensed Matter and Complex Systems (Search for Journal in Brave)

Abstract: A method of statistical description of thermodynamic properties of nanocrystals is developed. It is established that size-dependent quantization of vibrational modes results in formation of excess pressure of the phonon gas acting outwards the crystal. Based on the concept of the phonon gas pressure, size dependence of thermodynamic properties of nanocrystals was described, and size influence on a shift of a phase transformation temperature was explained.

Full work available at URL: https://arxiv.org/abs/1301.3310

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zbMATH Keywords

mesoscopic and nanoscale systems

Mathematics Subject Classification ID

Statistical mechanics of crystals (82D25)

Cited In (2)

• Molecular dynamics simulation of thermal stability of nanocrystalline vanadium
• Title not available (Why is that?)

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