Entropy and nonlinear nonequilibrium thermodynamic relation for heat conducting steady states

DOI10.1007/S10955-010-0095-5MaRDI QIDQ625530zbMATH OpenOpenAlexFDO

Authors Teruhisa S. Komatsu, Naoko Nakagawa, Shin-ichi Sasa, Hal Tasaki

Publication date 17 February 2011

Published in Journal of Statistical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1009.0970

zbMATH Keywords

nonequilibrium steady stateClausius relationexcess heat

Mathematics Subject Classification ID

Diffusion processes (60J60) Classical dynamic and nonequilibrium statistical mechanics (general) (82C05) Transport processes in time-dependent statistical mechanics (82C70) Dynamic renormalization group methods applied to problems in time-dependent statistical mechanics (82C28) Foundations of time-dependent statistical mechanics (82C03) Time-dependent statistical mechanics (dynamic and nonequilibrium) (82C99)

Abstract: Among various possible routes to extend entropy and thermodynamics to nonequilibrium steady states (NESS), we take the one which is guided by operational thermodynamics and the Clausius relation. In our previous study, we derived the extended Clausius relation for NESS, where the heat in the original relation is replaced by its "renormalized" counterpart called the excess heat, and the Gibbs-Shannon expression for the entropy by a new symmetrized Gibbs-Shannon-like expression. Here we concentrate on Markov processes describing heat conducting systems, and develop a new method for deriving thermodynamic relations. We first present a new simpler derivation of the extended Clausius relation, and clarify its close relation with the linear response theory. We then derive a new improved extended Clausius relation with a "nonlinear nonequilibrium" contribution which is written as a correlation between work and heat. We argue that the "nonlinear nonequilibrium" contribution is unavoidable, and is determined uniquely once we accept the (very natural) definition of the excess heat. Moreover it turns out that to operationally determine the difference in the nonequilibrium entropy to the second order in the temperature difference, one may only use the previous Clausius relation without a nonlinear term or must use the new relation, depending on the operation (i.e., the path in the parameter space). This peculiar "twist" may be a clue to a better understanding of thermodynamics and statistical mechanics of NESS.

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Cites work

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Cited in

(27)

• Exact equalities and thermodynamic relations for nonequilibrium steady states
• scientific article; zbMATH DE number 1230507 (Why is no real title available?)
• Heat and entropy in nonextensive thermodynamics
• Quantitative analysis of the Clausius inequality
• Excess entropy production in quantum system: quantum master equation approach
• Probable entropic nature of gravity in ultraviolet and infrared limits. Part I: An ultraviolet case
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• The McLennan-Zubarev steady state distribution and fluctuation theorems
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• Thermal contact through a diathermal wall: a solvable toy model
• Transport coefficients for a confined Brownian ratchet operating between two heat reservoirs
• The explicit form of the rate function for semi-Markov processes and its contractions
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• Extended Clausius relation and entropy for nonequilibrium steady states in heat conducting quantum systems
• Analysis of slow transitions between nonequilibrium steady states
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• Nonextensive thermodynamic relations based on the assumption of temperature duality
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