Charge inversion in colloidal systems

DOI10.1016/S0010-4655(02)00288-6zbMATH Open0994.82530arXivcond-mat/0201111OpenAlexW3105398580MaRDI QIDQ696532FDOQ696532

Authors: René Messina, Christian Holm, Kurt Kremer 

Publication date: 12 September 2002

Published in: Computer Physics Communications (Search for Journal in Brave)

Abstract: We investigate spherical macroions in the strong Coulomb coupling regime within the primitive model in salt-free environment. Molecular dynamics (MD) simulations are used to elucidate the effect of $discrete$ macroion charge distribution on charge inversion. A systematic comparison is made with the charge inversion obtained in the conventional continuous charge distribution. Furthermore the effect of multivalent counterions is reported.

Full work available at URL: https://arxiv.org/abs/cond-mat/0201111

zbMATH Keywords

molecular dynamicscharged colloids

Mathematics Subject Classification ID

Interacting particle systems in time-dependent statistical mechanics (82C22)

Cited In (1)

• A Random Batch Ewald Method for Particle Systems with Coulomb Interactions

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