Negative virial coefficients and the dominance of loose packed diagrams for D-dimensional hard spheres

DOI10.1023/B:JOSS.0000013960.83555.7DMaRDI QIDQ702929zbMATH OpenFDO

Authors Nathan Clisby, Barry M. McCoy

Publication date 19 January 2005

Published in Journal of Statistical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/cond-mat/0303100

zbMATH Keywords

Hard spheresvirial expansion

Mathematics Subject Classification ID

Critical phenomena in equilibrium statistical mechanics (82B27)

Abstract: We study the virial coefficients B_k of hard spheres in D dimensions by means of Monte-Carlo integration. We find that B_5 is positive in all dimensions but that B_6 is negative for all D >= 6. For 7<=k<=17 we compute sets of Ree-Hoover diagrams and find that either for large D or large k the dominant diagrams are "loose packed". We use these results to study the radius of convergence and the validity of the many approximations used for the equations of state for hard spheres.

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