Exact quantization rule to the Kratzer-type potentials: An application to the diatomic molecules

DOI10.1007/S10910-008-9438-8zbMATH Open1198.81217arXiv0802.0589OpenAlexW2111421995MaRDI QIDQ839360FDOQ839360

Authors: Sameer M. Ikhdair, Ramazan Sever 

Publication date: 2 September 2009

Published in: Journal of Mathematical Chemistry (Search for Journal in Brave)

Abstract: For any arbitrary values of $n$ and $l$ quantum numbers, we present a simple exact analytical solution of the $D$-dimensional ($Dgeq2$) hyperradial Schr% "{o}dinger equation with the Kratzer and the modified Kratzer potentials within the framework of the exact quantization rule (EQR) method. The exact energy levels $(E_{nl})$ of all the bound-states are easily calculated from this EQR method. The corresponding normalized hyperradial wave functions $\mathrm{\%}(ps{i}_{nl}(r))$ are also calculated. The exact energy eigenvalues for these Kratzer-type potentials are calculated numerically for the typical diatomic molecules $LiH,$ $CH,$ $HCl,$ $CO,$ $NO,$ $O_2,$ $N_2$ and $I_2$ for various values of $n$ and $l$ quantum numbers. Numerical tests using the energy calculations for the interdimensional degeneracy ($D=2-4$) for $I_2,$ $LiH,$ $HCl,$ $O_2,$ $NO$ and $CO$ are also given. Our results obtained by EQR are in exact agreement with those obtained by other methods.

Full work available at URL: https://arxiv.org/abs/0802.0589

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zbMATH Keywords

bound statesdiatomic moleculesexact quantization rulemodified Kratzer potential

Mathematics Subject Classification ID

Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Commutation relations and statistics as related to quantum mechanics (general) (81S05) Molecular physics (81V55)

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Cited In (32)

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• ROTATIONAL AND VIBRATIONAL DIATOMIC MOLECULE IN THE KLEIN–GORDON EQUATION WITH HYPERBOLIC SCALAR AND VECTOR POTENTIALS
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• Non-relativistic treatment of diatomic molecules interacting with a generalized Kratzer potential in hyperspherical coordinates

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