Combined theory of two- and four-component complete orthonormal sets of spinor wave functions and Slater type spinor orbitals in position, momentum and four-dimensional spaces

DOI10.1007/S10910-009-9582-9zbMATH Open1227.81159arXiv0812.2792OpenAlexW2594855381MaRDI QIDQ848170FDOQ848170

Authors: I. I. Guseinov 

Publication date: 2 March 2010

Published in: Journal of Mathematical Chemistry (Search for Journal in Brave)

Abstract: By the use of complete orthonormal sets of nonrelativistic scalar orbitals introduced by the author in previous papers the new complete orthonormal basis sets for two- and four-component spinor wave functions, and Slater spinor orbitals useful in the quantum-mechanical description of the spin- 1/2 particles by the quasirelativistic and Dirac's relativistic equations are established in position, momentum and four-dimensional spaces. These function sets are expressed through the corresponding nonrelativistic orbitals. The analytical formulas for overlap integrals over four-component relativistic Slater spinor orbitals with the same screening constants in position space are also derived. The relations obtained in this study can be useful in the study of different problems arising in the quasirelativistic and relativistic quantum mechanics when the position, momentum and four dimensional spaces are employed.

Full work available at URL: https://arxiv.org/abs/0812.2792

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zbMATH Keywords

Dirac equationoverlap integralsexponential type spinor orbitals

Mathematics Subject Classification ID

Closed and approximate solutions to the Schrödinger, Dirac, Klein-Gordon and other equations of quantum mechanics (81Q05) Spinor and twistor methods applied to problems in quantum theory (81R25) Atomic physics (81V45) Relativistic dynamics for problems in Hamiltonian and Lagrangian mechanics (70H40)

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• Unified treatment of complete orthonormal sets of functions in coordinate, momentum and four-dimensional spaces and their expansion and one-range addition theorems
• Unified treatment of complete orthonormal sets of nonrelativistic, quasirelativistic and relativistic sets of spinor wave functions, and Slater spinor orbitals in coordinate, momentum and four-dimensional spaces
• Unified treatment of complete orthonormal sets for wave functions, and Slater orbitals of particles with arbitrary spin in coordinate, momentum and four-dimensional spaces
• Natural Orbitals in the Quantum Theory of Two-Electron Systems

Cited In (9)

• On the mathematical nature of Guseinov's rearranged one-range addition theorems for Slater-type functions
• Unified treatment of complete orthonormal sets of functions in coordinate, momentum and four-dimensional spaces and their expansion and one-range addition theorems
• Unified treatment of complete orthonormal sets of nonrelativistic, quasirelativistic and relativistic sets of spinor wave functions, and Slater spinor orbitals in coordinate, momentum and four-dimensional spaces
• Unified treatment of complete orthonormal sets for wave functions, and Slater orbitals of particles with arbitrary spin in coordinate, momentum and four-dimensional spaces
• Theory of complete orthonormal sets of relativistic tensor wave functions and Slater tensor orbitals of particles with arbitrary spin in position, momentum and four-dimensional spaces
• Theory of complete orthonormal relativistic vector wave function sets and Slater type relativistic vector orbitals in coordinate, momentum and four-dimensional spaces
• On the unified treatment of complete orthonormal sets of functions in coordinate, momentum, and four dimensional spaces and their expansion and one-range addition theorems
• Unified treatment of complete orthonormal sets for exponential type vector orbitals of particles with spin 1 in coordinate, momentum and four-dimensional spaces
• Unified treatment of basis sets of relativistic exponential-type spinor orbitals for particles with arbitrary half-integral spin in position, momentum and four-dimensional spaces

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