The independence on boundary conditions for the thermodynamic limit of charged systems

DOI10.1007/S00220-005-1449-8MaRDI QIDQ852361zbMATH OpenOpenAlexWikidataFDO

Authors David Hasler, J. P. Solovej

Publication date 29 November 2006

Published in Communications in Mathematical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/math-ph/0411069

zbMATH Keywords

Coulomb interactionelastic boundary conditionsfermionsNeumann boundary conditionthermodynamic limit

Mathematics Subject Classification ID

Quantum equilibrium statistical mechanics (general) (82B10)

Abstract: We study systems containing electrons and nuclei. Based on the fact that the thermodynamic limit exists for systems with Dirichlet boundary conditions, we prove that the same limit is obtained if one imposes other boundary conditions such as Neumann, periodic, or elastic boundary conditions. The result is proven for all limiting sequences of domains which are obtained by scaling a bounded open set, with smooth boundary, except for isolated edges and corners.

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Cites work

• scientific article; zbMATH DE number 3622441 (Why is no real title available?)
• On the molecular limit of Coulomb gases
• Statistical mechanics of quantum mechanical particles with hard cores. I: The thermodynamic pressure
• The constitution of matter: existence of thermodynamics for systems composed of electrons and nuclei.
• The stability and instability of relativistic matter

Cited in

(5)

• A new approach to the modeling of local defects in crystals: The reduced Hartree-Fock case
• The thermodynamic limit for jellium
• Thermodynamic limit for dipolar media
• The free energy of systems with net charge
• Free energy density for continuous systems with and without superstability assumptions

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