Finite volume corrections and decay of correlations in the canonical ensemble

DOI10.1007/S10955-015-1207-ZMaRDI QIDQ888253zbMATH OpenOpenAlexFDO

Authors Elena Pulvirenti, Dimitrios Tsagkarogiannis

Publication date 30 October 2015

Published in Journal of Statistical Physics (Search for Journal in Brave)

Full work available at URL https://arxiv.org/abs/1409.2718

zbMATH Keywords

cluster expansioncorrelation functionscanonical ensemblefinite volume corrections

Mathematics Subject Classification ID

Interacting particle systems in time-dependent statistical mechanics (82C22)

Abstract: We consider a classical system of $N$ particles confined in a box $Lambdasubsetmathbb{R}^d$ interacting via a finite range pair potential. Given the validity of the cluster expansion in the canonical ensemble we compute the error between the finite and the infinite volume free energy and estimate it to be bounded by the area of the surface of the box's boundary over its volume. We also compute the truncated two-point correlation function and find that the contribution from the ideal gas case is of the order $1/N$ while the contribution of the interactions is of the order $1/|Lambda|$ plus an exponentially small error with the distance.

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• A simple inductive approach to the problem of convergence of cluster expansions of polymer models
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• Classical particles in the continuum subjected to high density boundary conditions
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• Revisiting Groeneveld's approach to the virial expansion
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