Large scale behavior of semiflexible heteropolymers
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disordertensor analysisheteropolymerlarge scale limitnon-commutative Fourier analysispersistence lengthsemiflexible chain
Central limit and other weak theorems (60F05) Brownian motion (60J65) Processes in random environments (60K37) Disordered systems (random Ising models, random Schrödinger operators, etc.) in equilibrium statistical mechanics (82B44) Statistical mechanics of polymers (82D60) Harmonic analysis on specific compact groups (43A75)
Abstract: We consider a general discrete model for heterogeneous semiflexible polymer chains. Both the thermal noise and the inhomogeneous character of the chain (the disorder) are modeled in terms of random rotations. We focus on the quenched regime, i.e., the analysis is performed for a given realization of the disorder. Semiflexible models differ substantially from random walks on short scales, but on large scales a Brownian behavior emerges. By exploiting techniques from tensor analysis and non-commutative Fourier analysis, we establish the Brownian character of the model on large scale and we obtain an expression for the diffusion constant. We moreover give conditions yielding quantitative mixing properties.
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Cites work
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- Polymers as self-avoiding walks
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Cited in
(5)- Kinetic models for semiflexible polymers in a half-plane
- Time dependent large principal deformation of polymers
- Influence of lattice disorder on the structure of persistent polymer chains
- Convergence of the freely rotating chain to the Kratky-Porod model of semi-flexible polymers
- Duality mapping and unbinding transitions of semiflexible and directed polymers
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