Quantum conditional quasi-solvability (exact solutions of the time-independent Schrödinger equation for a certain number of low-lying states if certain relations of the parameters hold)

Community: MathModDB

computational task

Available identifiers

MaRDI QIDQ6684604 FDOQ6684604

Description

For certain Hamiltonians, the concept of Conditional Quasi-Solvability holds: There are exact solutions of the time-independent Schrödinger equation for a certain number of low-lying quantum states (quasi-exact solvability), if and only if certain relations of the parameters of the Hamiltonian hold (conditionally exact solvability). For examples with trigonometric and hyperbolic potentials, see the annotating DOIs.

Contained entities

rotational constant
quantum eigen energy
quantum state vector (stationary)
quantum Hamiltonian (electric polarizability)	$H = H_{0} - \frac{1}{2} α ℰ^{2}$
	$H$ represents Hamiltonian operator
	$H_{0}$ represents Hamiltonian operator
	$α$ represents polarizability
	$ℰ$ represents electric field

quantum Hamiltonian (linear rotor)	$\hat{H} = B {\hat{J}}^{2}$
	$B$ represents rotational constant
	$J$ represents angular momentum operator
	$\hat{H}$ represents Hamiltonian operator

time-independent Schrödinger equation	$\hat{H} \| ψ_{n} ⟩ = E_{n} \| ψ_{n} ⟩$
	$E_{n}$ represents quantum eigen energy
	$H$ represents Hamiltonian operator
	$ψ_{n}$ represents quantum state vector (stationary)
	$n$ represents quantum number

quantum Hamiltonian (symmetric top)	$\hat{H} = A {\hat{J_{A}}}^{2} + B {\hat{J_{B}}}^{2} + C {\hat{J_{C}}}^{2}$
	$A$ represents rotational constant
	$B$ represents rotational constant
	$C$ represents rotational constant
	$J_{A}$ represents angular momentum operator
	$J_{B}$ represents angular momentum operator
	$J_{C}$ represents angular momentum operator
	$\hat{H}$ represents Hamiltonian operator

quantum Hamiltonian (electric dipole)	$H = H_{0} - μ \cdot ℰ$
	$H$ represents quantum Hamiltonian (electric dipole)
	$H_{0}$ represents Hamiltonian operator
	$ℰ$ represents electric field
	$μ$ represents electric dipole moment

Described at:

Conditional quasi-exact solvability of the quantum planar pendulum and of its anti-isospectral hyperbolic counterpart
Supersymmetry and eigensurface topology of the planar quantum pendulum
Supersymmetry and eigensurface topology of the spherical quantum pendulum
Symmetric Tops Subject to Combined Electric Fields: Conditional Quasi-Solvability via the Quantum Hamilton-Jacobi Theory
Topology of surfaces for molecular Stark energy, alignment, and orientation generated by combined permanent and induced electric dipole interactions

Further linked items

Item	Property
linear rotor (combined)	used by
symmetric top (combined)	used by

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