Quantum conditional quasi-solvability

exact solutions of the time-independent Schrödinger equation for a certain number of low-lying states if certain relations of the parameters hold

computational task

MaRDI QIDQ6684604FDOCommunityMathModDB

Description

For certain Hamiltonians, the concept of Conditional Quasi-Solvability holds: There are exact solutions of the time-independent Schrödinger equation for a certain number of low-lying quantum states (quasi-exact solvability), if and only if certain relations of the parameters of the Hamiltonian hold (conditionally exact solvability). For examples with trigonometric and hyperbolic potentials, see the annotating DOIs.

Contained entities

quantum eigen energy		output
quantum Hamiltonian (linear rotor)	$\hat{H} \equiv B {\hat{J}}^{2}$
	$B$ represents rotational constant
	$J$ represents angular momentum operator
	$\hat{H}$ represents quantum Hamiltonian (linear rotor)

time-independent Schrödinger equation	$\hat{H} \| ψ_{n} ⟩ = E_{n} \| ψ_{n} ⟩$
	$E_{n}$ represents quantum eigen energy
	$H$ represents Hamiltonian operator
	$ψ_{n}$ represents quantum state vector (stationary)
	$n$ represents quantum number

quantum Hamiltonian (symmetric top)	$\hat{H} \equiv A {\hat{J_{A}}}^{2} + B {\hat{J_{B}}}^{2} + C {\hat{J_{C}}}^{2}$
	$A$ represents rotational constant
	$B$ represents rotational constant
	$C$ represents rotational constant
	$J_{A}$ represents angular momentum operator
	$J_{B}$ represents angular momentum operator
	$J_{C}$ represents angular momentum operator
	$\hat{H}$ represents quantum Hamiltonian (symmetric top)

quantum Hamiltonian (electric polarizability)	$H \equiv H_{0} - \frac{1}{2} α ℰ^{2}$
	$H$ represents quantum Hamiltonian (electric polarizability)
	$H_{0}$ represents Hamiltonian operator
	$α$ represents polarizability
	$ℰ$ represents electric field

electric field	$E \equiv - \nabla ϕ$	output
	$E$ represents electric field
	$ϕ$ represents electric potential

rotational constant		input
quantum state vector (stationary)		output
quantum Hamiltonian (electric dipole)	$H \equiv H_{0} - μ \cdot ℰ$
	$H_{0}$ represents Hamiltonian operator
	$ℰ$ represents electric field
	$μ$ represents electric dipole moment
	$H$ represents quantum Hamiltonian (electric dipole)

References

Conditional quasi-exact solvability of the quantum planar pendulum and of its anti-isospectral hyperbolic counterpart
Supersymmetry and eigensurface topology of the planar quantum pendulum
Supersymmetry and eigensurface topology of the spherical quantum pendulum
Symmetric Tops Subject to Combined Electric Fields: Conditional Quasi-Solvability via the Quantum Hamilton-Jacobi Theory
Topology of surfaces for molecular Stark energy, alignment, and orientation generated by combined permanent and induced electric dipole interactions

Further links

Item	Property
linear rotor (combined)	used by
symmetric top (combined)	used by

Edit quantum conditional quasi-solvability item

This page was built for task: quantum conditional quasi-solvability