Sips isotherm model

Community: MathModDB

deterministic model

dimensional model

mathematical model

nonlinear model

static model

Available identifiers

MaRDI QIDQ6821134 FDOQ6821134

Also known as Langmuir–Freundlich isotherm

Description

The Sips isotherm model, also known as the Langmuir–Freundlich isotherm, is an empirical adsorption model developed to overcome the unbounded adsorption predicted by the classical Freundlich equation. It combines the heterogeneous surface characteristics of the Freundlich model with the finite monolayer adsorption limit of the Langmuir model. At low adsorbate concentrations, the Sips equation behaves like the Freundlich isotherm, while at sufficiently high concentrations it predicts a Langmuir-type saturation capacity. The model assumes localized adsorption without lateral interactions and is commonly used to describe heterogeneous adsorbent surfaces. Sips isotherm parameters are strongly influenced by system conditions such as pH, temperature, and solute concentration.

List of contained entities

Sips equation	$q_e=q_m\frac{K_S{C}_e^m}{1+K_S{C}_e^m}$
	$q_e$ represents adsorbed solute (equilibrium)
	$q_m$ represents maximum monolayer adsorption capacity
	$K_S$ represents Sips equilibrium constant
	$m$ represents Sips heterogeneity exponent
	$C_e$ represents solute concentration (equilibrium)

List of computational tasks

nonlinear parameter estimation (Sips model)

Described at:

Adsorptive removal of lead ions from wastewater using modified diatomite	(use)
Monolayer and multilayer adsorption isotherm models for sorption from aqueous media	(review)
On the Structure of a Catalyst Surface	(invention)

Mathematical models specializing Sips isotherm model

Langmuir adsorption model, Freundlich isotherm model

Further items linking to Sips isotherm model

Item	Property
chemical wastewater treatment	modelled by

This page was built for model: Sips isotherm model