quantum Hamiltonian (normal mode, anharmonic)
type: Item
instance of: mathematical expression
defining formula: H ^ = 1 2 <munderover> ∑ i = 1 3 N − 6 </munderover> ω i ( p ^ i 2 + q ^ i 2 ) + 1 6 ∑ i j k ϕ i j k q i q j q k + 1 24 ∑ i j k l ϕ i j k l q i q j q k q l
in defining formula: N
in defining formula: H ^
in defining formula: ω
in defining formula: ϕ i j k l
in defining formula: ϕ i j k
in defining formula: p ^
in defining formula: q ^
community: MathModDB
MaRDI profile type: MaRDI formula profile
specialized by: quantum Hamiltonian (normal mode, harmonic)
named after: William Rowan Hamilton
description: quantum-mechanical represention of molecular normal modes of vibration beyond the harmonic approximation