Hill-de Boer isotherm model
type: Item
instance of: mathematical model
instance of: deterministic model
instance of: dimensional model
instance of: static model
instance of: nonlinear model
community: MathModDB
MaRDI profile type: MaRDI model profile
description: The Hill–de Boer isotherm model is a theoretical adsorption model that accounts for lateral interactions and mobility among adsorbed molecules. It extends the Langmuir framework by incorporating an interaction energy term that captures attractive or repulsive forces between neighboring adsorbates. The model relates fractional surface coverage to equilibrium solute concentration through an exponential term derived from statistical thermodynamics. Because it includes interaction effects, it provides a more realistic description of adsorption on surfaces where adsorbate–adsorbate forces are significant. The Hill–de Boer model is used to analyze nonideal adsorption behavior in environmental, chemical, and surface science applications.
contains: Hill-de Boer equation
used by: nonlinear parameter estimation (Hill-de Boer model)
used by: linear parameter estimation (Hill-de Boer model)
described by source: Modelling and Interpretation of Adsorption Isotherms
named after: Jan Hendrik de Boer
named after: Terrell L. Hill
specialized by: Volmer isotherm model
description: mathematical model describing adsorption with lateral interactions