nonlinear parameter estimation (Elovich isotherm)

Community: MathModDB

computational task

nonlinear task

Available identifiers

MaRDI QIDQ6775816

nonlinear estimation of Elovich adsorption parameters from equilibrium data

Description

This task performs nonlinear parameter estimation using experimental adsorption equilibrium data. The objective is to determine the Elovich equilibrium constant and the Elovich maximum adsorption capacity by fitting the original nonlinear Elovich isotherm directly to measured equilibrium concentration and adsorbed amount data. Nonlinear regression avoids the distortions introduced by logarithmic transformation and generally provides more accurate estimates of both parameters. The resulting parameter values characterize adsorption affinity and the heterogeneous, energy-dependent adsorption behavior represented by the empirical Elovich model.

List of contained entities

Elovich equilibrium constant
Elovich isotherm equation	$\frac{q_e}{q_m}=K_E{c}_E\exp (-\frac{q_e}{q_m})$
	$q_e$ represents adsorbed solute (equilibrium)
	$q_m$ represents maximum monolayer adsorption capacity
	$K_E$ represents Elovich equilibrium constant
	$c_E$ represents solute concentration (equilibrium)
adsorbed solute (equilibrium)
maximum monolayer adsorption capacity
solute concentration (equilibrium)

Further items linking to nonlinear parameter estimation (Elovich isotherm)

Item	Property
Elovich isotherm model	used by

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