nonlinear parameter estimation (Hill adsorption model)

Community: MathModDB

computational task

nonlinear task

Available identifiers

MaRDI QIDQ6775832

nonlinear estimation of Hill adsorption model parameters, named after Terrell L. Hill

Description

This task performs nonlinear parameter estimation using equilibrium adsorption data applied to the Hill adsorption model. It determines the Hill adsorption constant, the maximum adsorption capacity, and the cooperativity exponent by directly fitting the nonlinear Hill isotherm to solute concentration and adsorbed-amount measurements. Nonlinear regression avoids structural distortions introduced by linearized forms and ensures accurate estimation of parameters across cooperative and non-cooperative regimes. The resulting parameters quantify adsorption affinity, surface saturation behavior, and cooperative interactions among adsorbed species. This approach is commonly used in environmental and materials science to analyze sigmoidal adsorption equilibria.

List of contained entities

Hill coefficient
Hill constant
Hill isotherm equation	$q_e=\frac{q_{SH}{C}_e^{n_H}}{K_D^{n_H}+C_e^{n_H}}$
	$n_H$ represents Hill coefficient
	$C_e$ represents solute concentration (equilibrium)
	$q_e$ represents adsorbed solute (equilibrium)
	$K_D$ represents Hill constant
	$q_{SH}$ represents Hill theoretical isotherm saturation capacity
Hill theoretical isotherm saturation capacity
adsorbed solute (equilibrium)
solute concentration (equilibrium)

Further items linking to nonlinear parameter estimation (Hill adsorption model)

Item	Property
Hill model (adsorption)	used by

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