linear parameter estimation (Temkin isotherm model)

Community: MathModDB

computational task

linear task

Available identifiers

MaRDI QIDQ6820957

linear estimation of Temkin isotherm parameters, named after Mikhail Temkin

Description

This task performs linear parameter estimation using adsorption equilibrium data by applying the linearized form of the Temkin isotherm. By plotting fractional coverage against the natural logarithm of solute concentration, the slope and intercept allow direct estimation of the adsorption-energy variation and the Temkin equilibrium constant. Although convenient, the linear method may introduce statistical bias due to transformation of variables. Nevertheless, it is widely used for rapid assessment of Temkin parameters in adsorption analysis. This approach is especially common in environmental and chemical engineering studies of pollutant adsorption.

List of contained entities

Temkin equilibrium constant
adsorption energy variation
fractional surface coverage	$\theta \equiv \frac{q_e}{q_m}$	input
	$\theta$ represents fractional surface coverage
	$q_e$ represents adsorbed solute (equilibrium)
	$q_m$ represents maximum monolayer adsorption capacity
linear Temkin isotherm equation	$\theta =\frac{RT}{\Delta Q}\ln (K_0)+\frac{RT}{\Delta Q}\ln (C_e)$
	$\theta$ represents fractional surface coverage
	$C_e$ represents solute concentration (equilibrium)
	$K_0$ represents Temkin equilibrium constant
	$\Delta Q$ represents adsorption energy variation
	$T$ represents temperature
	$R$ represents molar gas constant
solute concentration (equilibrium)

Further items linking to linear parameter estimation (Temkin isotherm model)

Item	Property
nonlinear parameter estimation (Temkin isotherm model)	linearized by
Temkin isotherm model	used by

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