linear parameter estimation (Fowler-Guggenheim isotherm model)

Community: MathModDB

computational task

linear task

Available identifiers

MaRDI QIDQ6820964

linear estimation of Fowler–Guggenheim parameters, named after Edward A. Guggenheim, Ralph H. Fowler

Description

This task estimates the Fowler–Guggenheim equilibrium constant and the interaction energy using the linearized form of the isotherm. Experimental equilibrium data are transformed and fitted using linear regression, providing a simplified estimation method. While computationally efficient, this approach may introduce bias from linearization. The results characterize the adsorption affinity and the sign and magnitude of lateral adsorption interactions.

List of contained entities

Fowler-Guggenheim equilibrium constant
fractional surface coverage	$\theta \equiv \frac{q_e}{q_m}$	input
	$\theta$ represents fractional surface coverage
	$q_e$ represents adsorbed solute (equilibrium)
	$q_m$ represents maximum monolayer adsorption capacity
interaction energy
linear Fowler-Guggenheim equation	$\ln (\frac{C_e(1-\theta )}{\theta })=-\ln (K_{FG})+\frac{2\theta W}{RT}$
	$C_e$ represents solute concentration (equilibrium)
	$\theta$ represents fractional surface coverage
	$K_{FG}$ represents Fowler-Guggenheim equilibrium constant
	$W$ represents interaction energy
	$R$ represents molar gas constant
	$T$ represents temperature
solute concentration (equilibrium)

Further items linking to linear parameter estimation (Fowler-Guggenheim isotherm model)

Item	Property
Fowler-Guggenheim isotherm model	used by
nonlinear parameter estimation (Fowler-Guggenheim isotherm model)	linearized by

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