nonlinear parameter estimation (Kiselev model)

Community: MathModDB

computational task

nonlinear task

Available identifiers

MaRDI QIDQ6820971

nonlinear estimation of Kiselev model parameters, named after Andrey Kiselyov

Description

This task performs nonlinear parameter estimation using adsorption equilibrium data to determine the Kiselev equilibrium constant and the complex formation constant. The nonlinear Kiselev equation is fitted directly to coverage and concentration values to capture the formation of complexes between adsorbed molecules. The results quantify adsorption affinity and the strength of lateral associative interactions. This method avoids potential distortions caused by linearization.

List of contained entities

Kiselev equation	$k_1{C}_e=\frac{\theta }{(1-\theta )(1+k_n\theta )}$
	$C_e$ represents solute concentration (equilibrium)
	$\theta$ represents fractional surface coverage
	$k_1$ represents Kiselev equilibrium constant
	$k$ represents complex formation constant
Kiselev equilibrium constant
complex formation constant
fractional surface coverage	$\theta \equiv \frac{q_e}{q_m}$	input
	$\theta$ represents fractional surface coverage
	$q_e$ represents adsorbed solute (equilibrium)
	$q_m$ represents maximum monolayer adsorption capacity
solute concentration (equilibrium)

Further items linking to nonlinear parameter estimation (Kiselev model)

Item	Property
Kiselev isotherm model	used by

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