linear parameter estimation (Kiselev model)

Community: MathModDB

computational task	linear task

Available identifiers

MaRDI QIDQ6820972

nonlinear estimation of Kiselev model parameters, named after Andrey Kiselyov

Description

This task estimates the Kiselev equilibrium constant and the complex formation constant using the linearized form of the Kiselev isotherm. Experimental equilibrium coverage and concentration data are transformed and analyzed using linear regression. Although computationally simple, the approach may introduce bias due to data transformation. The estimated parameters describe adsorption affinity and the extent of complex formation among adsorbed species.

List of contained entities

Further items linking to linear parameter estimation (Kiselev model)

Item	Property
Kiselev isotherm model	used by
nonlinear parameter estimation (Kiselev model)	linearized by

This page was built for task: linear parameter estimation (Kiselev model)

Kiselev equilibrium constant
complex formation constant
fractional surface coverage	$θ \equiv \frac{q_{e}}{q_{m}}$	input
	$θ$ represents fractional surface coverage
	$q_{e}$ represents adsorbed solute (equilibrium)
	$q_{m}$ represents maximum monolayer adsorption capacity

linear Kiselev equation	$\frac{1}{C_{e} (1 - θ)} = \frac{k_{1}}{t h e t a} + k_{1} k_{n}$
	$C_{e}$ represents solute concentration (equilibrium)
	$θ$ represents fractional surface coverage
	$k_{1}$ represents Kiselev equilibrium constant
	$k_{n}$ represents complex formation constant

solute concentration (equilibrium)