A relaxation model for liquid-vapor phase change with metastability (Q346000): Difference between revisions
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The purpose of this paper is to introduce a model which describes phase transitions for the van der Waals equation of state (EoS). First the thermodynamics of the system is described by the usual differential relations. Then a dynamical system is constructed, whose equilibria are either pure liquid/vapor, or a system of equations for the chemical potentials, pressures, etc. A theorem concerning the attractors of this system is proved by Lyapunov functions and the Gibbs relation. The different states are plotted in diagrams, and numerical illustrations are given by using Maxwell's equal area rule. A property of the Helmholtz free-energy is proved and the eigenvalues of the homogeneous system are computed. | |||
Property / review text: The purpose of this paper is to introduce a model which describes phase transitions for the van der Waals equation of state (EoS). First the thermodynamics of the system is described by the usual differential relations. Then a dynamical system is constructed, whose equilibria are either pure liquid/vapor, or a system of equations for the chemical potentials, pressures, etc. A theorem concerning the attractors of this system is proved by Lyapunov functions and the Gibbs relation. The different states are plotted in diagrams, and numerical illustrations are given by using Maxwell's equal area rule. A property of the Helmholtz free-energy is proved and the eigenvalues of the homogeneous system are computed. / rank | |||
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Property / reviewed by: Thomas Ernst / rank | |||
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Property / Mathematics Subject Classification ID: 35Q79 / rank | |||
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Property / Mathematics Subject Classification ID: 35L40 / rank | |||
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Property / Mathematics Subject Classification ID: 37N10 / rank | |||
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Property / Mathematics Subject Classification ID: 76T10 / rank | |||
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Property / Mathematics Subject Classification ID | |||
Property / Mathematics Subject Classification ID: 80A10 / rank | |||
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Property / Mathematics Subject Classification ID: 35B41 / rank | |||
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Property / zbMATH DE Number: 6659449 / rank | |||
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Property / zbMATH Keywords | |||
thermodynamics of phase transition | |||
Property / zbMATH Keywords: thermodynamics of phase transition / rank | |||
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metastable states | |||
Property / zbMATH Keywords: metastable states / rank | |||
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non-linear hyperbolic system with relaxation | |||
Property / zbMATH Keywords: non-linear hyperbolic system with relaxation / rank | |||
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Property / zbMATH Keywords | |||
van der Waals equation of state | |||
Property / zbMATH Keywords: van der Waals equation of state / rank | |||
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Property / MaRDI profile type: MaRDI publication profile / rank | |||
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Property / arXiv ID: 1507.06333 / rank | |||
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Latest revision as of 13:51, 18 April 2024
scientific article
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English | A relaxation model for liquid-vapor phase change with metastability |
scientific article |
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A relaxation model for liquid-vapor phase change with metastability (English)
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5 December 2016
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The purpose of this paper is to introduce a model which describes phase transitions for the van der Waals equation of state (EoS). First the thermodynamics of the system is described by the usual differential relations. Then a dynamical system is constructed, whose equilibria are either pure liquid/vapor, or a system of equations for the chemical potentials, pressures, etc. A theorem concerning the attractors of this system is proved by Lyapunov functions and the Gibbs relation. The different states are plotted in diagrams, and numerical illustrations are given by using Maxwell's equal area rule. A property of the Helmholtz free-energy is proved and the eigenvalues of the homogeneous system are computed.
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thermodynamics of phase transition
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metastable states
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non-linear hyperbolic system with relaxation
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van der Waals equation of state
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