Formula:6674524

Community: MathModDB

mathematical expression

Available identifiers

MaRDI QIDQ6674524

quantum-mechanical represention of molecular normal modes of vibration within the harmonic approximation, named after William Rowan Hamilton

Defining Formula: $\hat{H}=\frac{1}{2}\sum _{i=1}^{3N-6}{\omega }_i({\hat{p}}_i^2+{\hat{q}}_i^2)$

$N$ represents number of particles

$\hat{H}$ represents Hamiltonian operator

$\omega$ represents vibration frequency (harmonic)

$\hat{p}$ represents normal mode momentum (dimensionless)

$\hat{q}$ represents normal coordinate (dimensionless)

Further items linking to quantum Hamiltonian (normal mode, harmonic)

Item	Property
Hamiltonian operator	specialized by
normal mode (harmonic)	contains
quantum Hamiltonian (normal mode)	specialized by
quantum Hamiltonian (normal mode, anharmonic)	specialized by

This page was built for formula: quantum Hamiltonian (normal mode, harmonic)