nonlinear parameter estimation (Kiselev model) (Q6820971): Difference between revisions

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Property / contains
 
Property / contains: Kiselev equilibrium constant / rank
 
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Property / contains: Kiselev equilibrium constant / qualifier
 
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Property / contains: complex formation constant / rank
 
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Property / contains: complex formation constant / qualifier
 
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Property / contains: Kiselev equation / rank
 
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Property / linearized by
 
Property / linearized by: linear parameter estimation (Kiselev model) / rank
 
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Property / named after: Andrey Kiselyov / rank
 
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Latest revision as of 14:28, 1 December 2025

nonlinear estimation of Kiselev model parameters
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nonlinear parameter estimation (Kiselev model)
nonlinear estimation of Kiselev model parameters

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    This task performs nonlinear parameter estimation using adsorption equilibrium data to determine the Kiselev equilibrium constant and the complex formation constant. The nonlinear Kiselev equation is fitted directly to coverage and concentration values to capture the formation of complexes between adsorbed molecules. The results quantify adsorption affinity and the strength of lateral associative interactions. This method avoids potential distortions caused by linearization.
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