Nonequilibrium statistical mechanics of preasymptotic dispersion (Q1897040): Difference between revisions
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Latest revision as of 09:53, 30 July 2024
scientific article
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English | Nonequilibrium statistical mechanics of preasymptotic dispersion |
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Nonequilibrium statistical mechanics of preasymptotic dispersion (English)
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1994
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We provide a nonequilibrium statistical mechanical theory of transport which involves both diffusive and convective mixing (dispersion) at all scales. The theory is based on a generalization of classical approaches used in molecular hydrodynamics and on time-correlation functions defined in terms of nonequilibrium expectations. The resulting constitutive laws are nonlocal, and constitutive parameters are wavevector and frequency dependent. All results reduce to their convolution-Fickian, quasi- Fickian, or Fickian counterparts in the appropriate limits.
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nonlocal constitutive laws
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fractal characters
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heterogeneity
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dispersion
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time-correlation functions
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