Curve fitting and identification of physical spectra (Q1919511): Difference between revisions
From MaRDI portal
Added link to MaRDI item. |
Set profile property. |
||
Property / MaRDI profile type | |||
Property / MaRDI profile type: MaRDI publication profile / rank | |||
Normal rank |
Revision as of 07:17, 5 March 2024
scientific article
Language | Label | Description | Also known as |
---|---|---|---|
English | Curve fitting and identification of physical spectra |
scientific article |
Statements
Curve fitting and identification of physical spectra (English)
0 references
5 January 1997
0 references
The identification of peak superpositions and the determination of the single-peak intensities are studied on the model function \[ \eta(a, x, t):= \sum^q_{i= 1} a_i \exp\Biggl(- {(t- x_i)^2\over 2x^2_{i+ q}}\Biggr)+ a_{q+ 1} t^2+ a_{q+ 2} t+ a_{q+ 3}. \] The composition of the parameters \(a_i\), \(a_{q+ i}\), and \(x_i\) in the model function is evaluated. A modification of the trust-region Gauss-Newton method for the solution of separable nonlinear least squares problem is used (with a two-parameter approximation). The method of regularized variable projection is described to find an algorithm (its 7 steps are given) for the approximation. An application of the method for the identification of spectra of X-ray emission analyses (Ta, Mo, Ga phosphide, chromium manganese, and 3 other analyses) is studied.
0 references
curve fitting
0 references
identification of physical spectra
0 references
trust-region Gauss-Newton method
0 references
nonlinear least squares problem
0 references
method of regularized variable projection
0 references
algorithm
0 references
X-ray emission
0 references