Large deviations and the equivalence of ensembles for Gibbsian particle systems with superstable interaction (Q1333563): Difference between revisions
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Latest revision as of 09:46, 30 July 2024
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English | Large deviations and the equivalence of ensembles for Gibbsian particle systems with superstable interaction |
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Large deviations and the equivalence of ensembles for Gibbsian particle systems with superstable interaction (English)
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13 October 1994
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For Gibbsian systems of particles in \(\mathbb{R}^ d\), we investigate large deviations of the translation invariant empirical fields in increasing boxes. The particle interaction is given by a superstable, regular pair potential. The large deviation principle is established for systems with free or periodic boundary conditions and, under a stronger stability hypothesis on the potential, for systems with tempered boundary conditions, and for tempered (infinite-volume) Gibbs measures. As a by- product we obtain the Gibbs variational formula for the pressure. We also prove the asymptotic equivalence of microcanonical and grand canonical Gibbs distributions and establish a variational expression for the thermodynamic entropy density.
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Gibbsian systems of particles
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translation invariant empirical fields
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microcanonical
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grand canonical
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thermodynamic entropy density
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