A model of dilute polymer solutions with hydrodynamic interaction and finite extensibility. I: Basic equations and series expansions (Q1098370): Difference between revisions
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English | A model of dilute polymer solutions with hydrodynamic interaction and finite extensibility. I: Basic equations and series expansions |
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A model of dilute polymer solutions with hydrodynamic interaction and finite extensibility. I: Basic equations and series expansions (English)
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1987
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A bead-spring chain model is used to describe dilute polymer solutions. Two important effects, the hydrodynamic interaction between the beads of a single chain and the finite extensibility of the springs connecting the beads, are treated in a self-consistently averaged form. For the resulting model, a rheological equation of state, a third-order retarded- motion expansion, and a second-order codeformational memory-integral expansion are derived. Furthermore, the parameters characterizing the model and the limit of infinitely long chains are discussed in great detail.
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bead-spring chain model
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dilute polymer solutions
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hydrodynamic interaction
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rheological equation
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third-order retarded-motion expansion
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second-order codeformational memory-integral expansion
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limit of infinitely long chains
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