Nonequilibrium statistical mechanics of preasymptotic dispersion (Q1897040)

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Nonequilibrium statistical mechanics of preasymptotic dispersion
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    Nonequilibrium statistical mechanics of preasymptotic dispersion (English)
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    1994
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    We provide a nonequilibrium statistical mechanical theory of transport which involves both diffusive and convective mixing (dispersion) at all scales. The theory is based on a generalization of classical approaches used in molecular hydrodynamics and on time-correlation functions defined in terms of nonequilibrium expectations. The resulting constitutive laws are nonlocal, and constitutive parameters are wavevector and frequency dependent. All results reduce to their convolution-Fickian, quasi- Fickian, or Fickian counterparts in the appropriate limits.
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    nonlocal constitutive laws
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    fractal characters
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    heterogeneity
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    dispersion
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    time-correlation functions
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