Analysis of nonequilibrium dissociation kinetics in a boundary layer using various reaction models

MaRDI QIDQ2760803zbMATH OpenFDO

Authors G. Ya. Dynnikova, N. K. Makashev, E. A. Rastigeev

Publication date 13 December 2001

Published in Prikladnaya Mekhanika i Tekhnicheskaya Fizika (Search for Journal in Brave)

zbMATH Keywords

chemical kineticdiatomic molecules dissociationkinetic of vibrational levelsnonisothermal boundary layer

Mathematics Subject Classification ID

Chemical kinetics in thermodynamics and heat transfer (80A30) Dynamic and nonequilibrium phase transitions (general) in statistical mechanics (82C26) Kinetic theory of gases in time-dependent statistical mechanics (82C40)

Review text

Values of the nonequilibrium macroscopic reaction rate for a nonisothermal boundary layer of a monatomic diluent gas are calculated using a number of models for thermal dissociation of diatomic molecules as anharmonic Morse oscillators. Analysis is performed for conditions where the diffusive transfer of excited molecules has a significant effect on the population of their upper vibrational levels, which does not only amount to change in vibrational temperature. Under the joint influence of diffusive transfer of molecules, vibrational exchanges, and reactions involving vibrationally excited particles, the local vibrational distribution functions are substantially nonequilibrium. The kinetic models considered take into account the possible contribution of the energy of molecular translational and rotational degrees of freedom to the energy required to overcome the reaction threshold. The effect of multiquantum vibrational-translational exchanges on the distribution of dissociating molecules in their upper vibrational levels is taken into account approximately.

Recommendations

• Thermal dissociation of diatomic molecules in a nonisothermal boundary layer in the presence of exchange reactions
• Nonequilibrium dissociation of diatomic molecules in flows with convective and diffusive particle transport
• The effect of nonequilibrium dissociation on boundary layer flow
• Estimation of the effect of vibrational excitation of diatomic molecules on their diffusional transport and dissociation in a boundary layer
• Characteristic features of boundary layers in vibration-dissociation non-equilibrium

Cited in

(10)

• Nonequilibrium dissociation of diatomic molecules in flows with convective and diffusive particle transport
• Estimation of the effect of vibrational excitation of diatomic molecules on their diffusional transport and dissociation in a boundary layer
• A model for isothermal homogeneous-heterogeneous reactions in boundary-layer flow
• Inverse Laplace transformation for evaluation of state-specific cross sections for dissociation reaction and vibrational energy transitions
• Rotation-vibration-dissociation interaction in a multicomponent nonequilibrium viscous shock layer
• Dissociation rate constants in nonequilibrium flows
• Thermal dissociation of diatomic molecules in a nonisothermal boundary layer in the presence of exchange reactions
• The effect of nonequilibrium dissociation on boundary layer flow
• Characteristic features of boundary layers in vibration-dissociation non-equilibrium
• Time-dependent concentrations of reagents and products involved in the dissociation-recombination process

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