Analytical evaluation of zero-pressure Joule-Thomson coefficient using second virial coefficient and its application

DOI10.1007/S10910-016-0702-ZMaRDI QIDQ1704733zbMATH OpenOpenAlexFDO

Authors Bahtiyar A. Mamedov, Elif Somuncu

Publication date 13 March 2018

Published in Journal of Mathematical Chemistry (Search for Journal in Brave)

Full work available at URL https://doi.org/10.1007/s10910-016-0702-z

zbMATH Keywords

Lennard-Jones (12-6) potentialsecond virial coefficientzero-pressure Joule-Thomson coefficient

Mathematics Subject Classification ID

Foundations of thermodynamics and heat transfer (80A05) Statistical thermodynamics (82B30)

Review text

The authors propose a numerical resolution for the zero-pressure Joule-Thomson coefficient through that of the second virial coefficient over the Lennard-Jones (12-6) potential, which was presented in their previous paper [``Analytical treatment of second virial coefficient over Lennard-Jones (\(2n-N\)) potential and its application to molecular sytems, J. Mol. Struct. 1068, 164--169 (2014; \url{doi:10.1016/j.molstruc.2014.04.006}), corrigendum ibid. 1141, 593 (2017; \url{doi:10.1016/j.molstruc.2017.04.012})]. The expression of the Joule-Thomson coefficient contains \(\Gamma \)-functions. The authors illustrate their computations taking different gases and they compare their results with previously obtained ones.

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Cites work

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Cited in

(4)

• Joule-Thomson coefficient in systems with multiple chemical equilibria
• Second virial coefficient for the Lennard-Jones potential
• A comparative evaluation of speed of sound and specific heat capacities of gases by using the quantum mechanical and classical second virial coefficients
• Thermodynamic analysis based on the second-order variations of thermodynamic potentials

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