Gibb's variational principles for the equilibrium of continuous systems with an interface
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A mathematical formulation of Gibbs variational principle is supplied for the equilibrium of a system of two fluids with an interface adsorbing or not and permeable or not. These properties of the interface are represented by suitable constraints for the admissible variations.
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Cites work
Cited in
(4)- Invariance of free energy against a shift of the dividing surface of arbitrary geometry
- Properties of the Gibbs potential and the equilibrium of a liquid with its vapor
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